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Yes you could for from Rome Val d orcia is 3 hours away. This spot is an one day excursion spot. You could spend hours in this spot, for from val d orcia, Florence is 3 hours away.
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Valdochiana is the place to get off when you travel from Rome to start exploring before val d orcia
While it is technically possible to make a detour to visit Val d'Orcia when traveling from Rome to Florence, it would be quite ambitious to cover the region in a single day. Val d'Orcia, located in Tuscany, is known for its stunning landscapes, charming villages, and rolling hills. The drive from Rome to Val d'Orcia takes around 2.5 to 3.5 hours, depending on the specific destination within Val d'Orcia. Once there, you'll want to explore the picturesque towns such as Pienza, Montalcino, and Montepulciano, each with its own unique character. Considering the travel time, exploring Val d'Orcia, and then continuing to Florence, it would be a rushed experience. If you have the flexibility, it might be more enjoyable to dedicate a separate day or more to fully appreciate the beauty of Val d'Orcia. Alternatively, you could plan a visit to a specific town in Val d'Orcia on your way from Rome to Florence, allowing for a brief stop and exploration without compromising your overall schedule. denatrip.com
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